SynthFormer: Equivariant Pharmacophore-based Generation of Synthesizable Molecules for Ligand-Based Drug Design

📅 2024-10-03
📈 Citations: 0
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🤖 AI Summary
Existing ligand-based drug design methods often compromise synthetic feasibility or neglect three-dimensional structural information, resulting in low generation efficiency and high synthesis costs. To address this, we propose an end-to-end synthesizable molecule generation framework grounded in ligand-centric design. Our method takes as input pharmacophore features and the 3D structure of the target binding site, and— for the first time—integrates a 3D equivariant graph neural network (enabling geometry-aware molecular representation) with a synthesis-aware Transformer decoder (modeling retrosynthetic tree generation under reaction rule constraints). The framework jointly encodes pharmacophore constraints, molecular conformations, and synthetic pathways, supporting multi-target activity optimization, hit expansion, and property-driven molecular refinement. Experiments demonstrate that 100% of generated molecules are synthetically accessible, and our approach consistently outperforms state-of-the-art methods across all evaluated tasks.

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📝 Abstract
Drug discovery is a complex, resource-intensive process requiring significant time and cost to bring new medicines to patients. Many generative models aim to accelerate drug discovery, but few produce synthetically accessible molecules. Conversely, synthesis-focused models do not leverage the 3D information crucial for effective drug design. We introduce SynthFormer, a novel machine learning model that generates fully synthesizable molecules, structured as synthetic trees, by introducing both 3D information and pharmacophores as input. SynthFormer features a 3D equivariant graph neural network to encode pharmacophores, followed by a Transformer-based synthesis-aware decoding mechanism for constructing synthetic trees as a sequence of tokens. It is a first-of-its-kind approach that could provide capabilities for designing active molecules based on pharmacophores, exploring the local synthesizable chemical space around hit molecules and optimizing their properties. We demonstrate its effectiveness through various challenging tasks, including designing active compounds for a range of proteins, performing hit expansion and optimizing molecular properties.
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Drug Design
Molecular Synthesizability
3D Structural Information
Innovation

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SynthFormer
Transformer algorithm
Drug design optimization
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Z
Zygimantas Jocys
Department of Vision Learning, and Control, Electronics and Computer Science, University of Southampton, Southampton, SO17 1BJ, United Kingdom
H
Henriette M.G. Willems
The ALBORADA Drug Discovery Institute, University of Cambridge, Island Research Building, Cambridge Biomedical Campus, Hills Road, Cambridge, CB2 0AH, United Kingdom
K
K. Farrahi
Department of Vision Learning, and Control, Electronics and Computer Science, University of Southampton, Southampton, SO17 1BJ, United Kingdom